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Windows doesn't like simple copies. there is a lot happening in a windows system in regards to file properties/security and permissions. MUCH better to re-install windows and associated programs and data fresh. and if at all possible get rid of XP. Unless you have an extremely good reason to keep it, and the PC will NEVER be connected to any network, USB device, or even within soundwave distance of any other device connected to the internet...get rid of it.
it is possible you have raw copied a damaged installation. think of it like having a picture with a Sharpie mark on it, and then you photocopy it expecting it to copy only the picture but the mark is still there.
If you really want to get into the weeds of why, you need to look at the hardware - is it all ok? are the capacitors on the mainboard gone? Any issue with RAM, VGA card not faulty? Drivers all up to date? any file corruption, is windows patched properly? Any conflicts or buggy patches? Are the HDDs all good? have you looked in eventlog (eventvwr.exe) for why it has crashed?
IMHO a lot of work tracking something down akin to trying to find out the exact source of the cold you picked up... - just fix it and move on
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