Several possible options, and since this isn't a Windows or PC or radio support forum

you may get better help in those areas elsewhere. My initial thoughts are:
senorpena wrote:
My work windows laptop (USB 2.0) will not recognize it & in fact states it needs to be formatted but the laptop fails to format it when I tried.
Since you mention another PC works OK with the same 64GB drives, then this seems to be a laptop-specific issue (perhaps specific to the OS installation on that PC). Therefore that is where I would focus, if I was in your position.
senorpena wrote:
My USB enabled radios will not recognize the drives & cannot read them but will accept 32GB/16GB/8GB sticks that I have.
I've seen USB radios which have limits on the maximum capacity of drives they can use. Based on your comments, and assuming that the 64GB drives are confirmed OK from your tests with your PC & Mac, then possible reasons include - either the 64GB drives are drawing more current than the radios are designed to provide; or they are a greater capacity than the radios are designed to work with; or they have not been partitioned in a compatible way (some USB radios would use the first 32GB partition on a 64GB drive, for example). Again, this seems to be an equipment (radio) issue / limitation, since you seem to be saying that the 64GB drives work OK elsewhere.
Just to be on the safe side, I would fully test (write / read / compare - multiple times) those 64GB drives on a PC where they
seem to work now, to get some confidence in the drives themselves, before relying on them for important data, and to reduce the chances of you being misled in case your odd results are actually due to any strange behaviour of the drives.
Hope that gives you some suggestions of things to consider in your testing.