Well, the problem has been solved but...
First, thank you for the suggestion. I'm not running Synchback or any sync software (at least I don't think I am) but I did another thorough search of the running processes and startups (via msconfig & autorun) and nothing stood out. It was a good suggestion as it most certainly could have been something of that ilk.
What happened and "worked": The short answer is "I don't know exactly what fixed it but it's fixed". I went though yet another (many) re-boots and every time the SSD filled to capacity with the trace file - I want to say it was a 46Gb file! My usual work-around is to delete it and the C: drive (with the subsequent extra 46Gb of free space) is just fine until the next boot. I noticed that the timestamp of the log/trace file was "at the time of the boot" and not some previous date/time (e.g. when it was originally created). I got in to XPERF (a somewhat cryptic command line utility) and WPR (Windows Performance Recorder) and "entered a few commands" (de-checked all boxes in the graphic interface although there is no button to save that information so I'm not sure it did anything). I stopped the hash table recording in XPERF and tried other options with subsequent error messages. Now I boot and there are no trace files generated; my C: drive has that 46Gb of headroom. Sorry - I just don't know what it was that stopped it (or what was causing it in the first place).
Note that there was no option to de-install (remove program) for XPERF or WPR/WPA. Also, I never saw any process/task queued up/running (via msconfig or autoruns or any task manager) so I have no idea on what kicks it off and as such how to stop if from running as such. I also don't know what was in the enormous trace file (I'd suspect it was an appended file across multiple boots and not a new from scratch one but I can't verify that) as I couldn't run the analyzer as I got choked out due to disk space. If it was building upon the old/deleted file, I don't know how it did that.
I hope that this helps somebody in the future. I'm certain that there are some/many significantly more competent than I am at using XPERF and WPR/WPA; right now I'm not looking to become an "expert". Suffice it to say that XPERF & WPR are idiosyncratic...
